Program > Browse abstracts by speaker > Perrillat Jean-Philippe

Reactive transport of carbonatite melts: insights from HP-HT infiltration experiments
Jean-Philippe Perrillat  1@  , Elena Giovenco  2@  , Noah Collin  3@  , Eglantine Boulard  4@  , Le Godec Yann  4@  , King Andrew  5@  , Henry Laura  5@  , Guignot Nicolas  5@  
1 : Laboratoire de Géologie de Lyon  (UMR5276)
Université Claude Bernard Lyon 1, ENS de Lyon, CNRS
2 : Laboratoire de Géologie de Lyon  (UMR5276)
Universié Claude Bernard Lyon 1, CNRS, Ens de Lyon
3 : Laboratoire de Géologie de Lyon  (UMR5276)
Université Claude Bernard Lyon 1, CNRS, Ens de Lyon
4 : Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie  (UMR 7590)
Sorbonne Université, CNRS, MNHN, IRD, F-75252 Paris, France
5 : Synchrotron Soleil
PSICHE Beamline, Synchrotron SOLEIL

Carbonatite melts can play a crucial role in the deep carbon cycle, as major carbon carriers from the deep Earth to its surface. Indeed, due to their low viscosities (

In this work, we performed high-pressure/high-temperature infiltration experiments in peridotite minerals powders to investigate mantle metasomatism by those unusual magmas, as well as the dynamics and morphology of carbonate melt migration. Using real-time computed tomography (CT) imaging under extreme conditions (PSICHE beamline, Synchrotron SOLEIL) and Raman plus SEM-EDS on quenched samples (Laboratoire de Géologie de Lyon), we provide insights into the kinetics of melt infiltration and reactivity. Time-lapsed CT images exhibit the diffusive dynamics of capillary flow, and the observed infiltration rates of 5.3 – 5.9 mm/h confirm the high mobility of carbonate liquids relative to silicate ones. Chemical reactivity corresponding to matrix wherlitization was also observed on a time scale comparable to that of the melt flow. Further experiments on the assimilation of orthopyroxene into carbonate melts at 2 GPa-1000°C provide constraints on the mechanism and kinetics of orthopyroxene dissolution, and its effect on the evolution of the composition and physical properties of the melt.


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